One is quantifiable ... the other can only be assessed if there is evidence in place for verification.
Would it be presumptive of me to assume that you already know this?
So your detector is set for silver and it alarms at something underground. How confident are you it is silver before you dig? it could be copper which within normal operating constraints has a not dissimilar conductivity.
We have done the dog bit before about its olfactory senses being so acute it could smell something not detectable by human eye or device. Because you can't see it or detect it does not mean it is not there.
Back to the plot. Should the dog or detector alarm my first reaction will be it has alarmed to what it should have on the basis it is calibrated [trained] properly. If it isn't why the hell are you using it? That is a rhetorical question btw.
To determine what precisely triggered the alarm will require operator intervention. In the case of the detector a shovel and metallurgist will come in handy. In the case of the dog there is the added disadvantage detailed in the first para above.
I think what I mean should now be quite clear. Although you do need to understand the concept of no single right answer.