I thought that was a good point. If we can see traces of Luminol we might think we are approaching a crime scene. So they must have thoroughly cleaned the apartment after the PJ left.
No doubt the dog could sense luminol. How that alters Eddie's response is unknown.
I agree with G-Unit that the unnamed chemical used was probably Luminol.
We have only seen video of areas associated with McCann which makes it impossible to assess the dog's reaction on approach to other places ... but Martin Grime makes reference to the dog becoming excitable as he walked along the pathway to the door of 5A.
To the extent that he did not obey the 'sit' command prior to entry. We saw it demonstrated in the garage sequence that he was trained to sit and then given the command to search.
We've seen the window which the dog had to pass covered in dragon's blood (fingerprint powder) precisely the area as noted by Martin Grime, where his intense interest began.
We have also seen his lengthy inspection of the apartment sniffing everywhere and anywhere before eventually barking.